{ "id": "cond-mat/0207299", "version": "v1", "published": "2002-07-11T18:24:07.000Z", "updated": "2002-07-11T18:24:07.000Z", "title": "Electronic and optical properties of LiBC", "authors": [ "A. V. Pronin", "K. Pucher", "P. Lunkenheimer", "A. Krimmel", "A. Loidl" ], "comment": "4 pages, 4 figures", "journal": "Phys. Rev. B 67, 132502 (2003)", "doi": "10.1103/PhysRevB.67.132502", "categories": [ "cond-mat.mtrl-sci", "cond-mat.supr-con" ], "abstract": "LiBC, a semiconducting ternary borocarbide constituted of the lightest elements only, has been synthesized and characterized by x-ray powder diffraction, dielectric spectroscopy, and conductivity measurements. Utilizing an infrared microscope the phonon spectrum has been investigated in single crystals. The in-plane B-C stretching mode has been detected at 150 meV, noticeably higher than in AlB2, a non-superconducting isostructural analog of MgB2. It is this stretching mode, which reveals a strong electron-phonon coupling in MgB2, driving it into a superconducting state below 40 K, and is believed to mediate predicted high-temperature superconductivity in hole-doped LiBC [H. Rosner, A. Kitaigorodsky, and W. E. Pickett, Phys. Rev. Lett. 88, 127001 (2002)].", "revisions": [ { "version": "v1", "updated": "2002-07-11T18:24:07.000Z" } ], "analyses": { "keywords": [ "optical properties", "electronic", "mediate predicted high-temperature superconductivity", "x-ray powder diffraction", "in-plane b-c stretching mode" ], "tags": [ "journal article" ], "publication": { "publisher": "APS", "journal": "Phys. Rev. B" }, "note": { "typesetting": "TeX", "pages": 4, "language": "en", "license": "arXiv", "status": "editable" } } }